Led with phosphor tile and overmolded phosphor in lens

ABSTRACT

Overmolded lenses and certain fabrication techniques are described for LED structures. In one embodiment, thin YAG phosphor plates are formed and affixed over blue LEDs mounted on a submount wafer. A clear lens is then molded over each LED structure during a single molding process. The LEDs are then separated from the wafer. The molded lens may include red phosphor to generate a warmer white light. In another embodiment, the phosphor plates are first temporarily mounted on a backplate, and a lens containing a red phosphor is molded over the phosphor plates. The plates with overmolded lenses are removed from the backplate and affixed to the top of an energizing LED. A clear lens is then molded over each LED structure. The shape of the molded phosphor-loaded lenses may be designed to improve the color vs. angle uniformity. Multiple dies may be encapsulated by a single lens. In another embodiment, a prefabricated collimating lens is glued to the flat top of an overmolded lens.

CROSS-REFERENCE TO RELATED APPLICATIONS

This is a continuation-in-part (CIP) of U.S. application Ser. No.11/093,961, filed Mar. 29, 2005, entitled “Wide Emitting Lens for LEDUseful for Backlighting,” by Willem Smits, Grigorily Basin, et al.,which is a CIP of U.S. application Ser. No. 11/069,418, filed Feb. 28,2005, by Grigoriy Basin et al., entitled “Overmolded Lens Over LED Die,”which is a CIP of U.S. application Ser. No. 10/990,208, filed Nov. 15,2004, by Grigoriy Basin et al., entitled “Molded Lens Over LED Die,” allincorporated herein by reference.

FIELD OF THE INVENTION

This invention relates to light emitting diodes (LEDs) and, inparticular, to certain lens designs and a technique for forming a lensover an LED die.

BACKGROUND

LED dies typically emit light in a lambertian pattern. It is common touse a lens over the LED die to narrow the beam or to make aside-emission pattern. A common type of lens for a surface mounted LEDis preformed molded plastic, which is bonded to a package in which theLED die is mounted. One such lens is shown in U.S. Pat. No. 6,274,924,assigned to Philips Lumileds Lighting Company and incorporated herein byreference.

SUMMARY

A technique for forming a molded lens for surface mounted LEDs isdescribed herein along with various designs of lenses. Also describedare various techniques for providing color converting phosphors withinthe lens.

In one method for forming lenses, one LED die or multiple LED dice aremounted on a support structure. The support structure may be a ceramicsubstrate, a silicon substrate, or other type of support structure withthe LED dice electrically connected to metal pads on the supportstructure. The support structure may be a submount, which is mounted ona circuit board or a heat sink in a package.

A mold has indentations in it corresponding to the positions of the LEDdice on the support structure. The indentations are filled with aliquid, optically transparent material, such as silicone, which whencured forms a hardened lens material. The shape of the indentations willbe the shape of the lens. The mold and the LED dice/support structureare brought together so that each LED die resides within the liquid lensmaterial in an associated indentation.

The mold is then heated to cure (harden) the lens material. The mold andthe support structure are then separated, leaving a complete lens overeach LED die. This general process will be referred to as overmolding.In contrast to injection molding techniques where the liquid material isinjected at high pressure after the empty mold is encased around theobject to be encapsulated, the present invention uses no such injectionand the LED and any wire bonds are not stressed by the molding process.Also, there is very little waste of the lens material. Further, thereare no conduits between mold indentions, as would be required forinjection molding.

The overmolding process may be repeated with different molds to createoverlapping shells of lenses. The lenses may contain any combinations ofphosphors to convert the LED light to any color, including white.

In one embodiment, thin ceramic phosphor plates are formed by sinteringphosphor grains under heat and pressure or by drying a slurry ofphosphor grains. Each plate has a surface approximately the size of thetop surface of the energizing LED, such as a blue LED. The phosphor maybe YAG phosphor, where the combination of the blue light from the LEDand the green-yellow light from the YAG phosphor produces white light.The plates may be affixed over LEDs mounted on a submount wafer, and aclear lens is then molded over each LED structure. The submount is thensingulated to separate the LED structures.

In another embodiment, the molded lens over the LED and YAG phosphorplate includes red phosphor to generate a warmer white light.

In another embodiment, the phosphor plates are first temporarily mountedon a backplate, and a lens containing a red phosphor is molded over thephosphor plates. The plates with overmolded lenses are removed from thebackplate and affixed to the top of an energizing LED. A clear lens isthen molded over each LED structure.

Since the phosphor plate is flat, the color temperature becomes hotter(more blue) as the viewing angle approaches an angle normal to thesurface of the LED/phosphor. To compensate for this color vs. anglenon-uniformity, the shape of the mold containing the red phosphor isdefined so that the color temperature is more uniform as the viewingangle changes. The shape of the mold is therefore dependent on theparticular LED and phosphor plate used.

In one embodiment, the cured silicone used to form the outer lens byovermolding is much harder than any inner lens formed by overmolding.The softer inner lens does not put stress on the delicate LED when thelens is being formed or when the LED generates heat, while the hardouter lens protects against the outside elements and remains clean.

In another embodiment, multiple LEDs or an LED and another chip, such asfor electrostatic discharge (ESD) protection, are encapsulated by asingle overmolded lens, where the shape of the lens is based on theparticular chips being encapsulated.

In another embodiment, an molded lens is formed over an LED, where thelens may be clear or phosphor loaded. The top of the lens has a flatportion. A prefabricated collimating lens, such as a Fresnel lens,approximately the same size as the LED, is then affixed to the flatportion of the overmolded lens. Such a small collimated light source isparticularly useful as a cell phone camera flash.

In another embodiment, a soft silicone gel is used as an underfillbetween the LED and the submount to fill in any voids. The underfill mayoptionally coat the sides of the LED. The resulting structure is thenovermolded with a hard lens. The underfill helps support the LED dieduring processing and operation, couples heat to the submount, andreduces stress between the LED die and the hard outer lens.

Many other embodiments of lenses and applications are described.

BRIEF DESCRIPTION OF THE DRAWINGS

FIG. 1 is a side view of four LED dice mounted on a support structure,such as a submount, and a mold for forming a lens around each LED die.

FIG. 2 is a side view of the LED dice being inserted into indentationsin the mold filled with a liquid lens material.

FIG. 3 is a side view of the LED dice removed from the mold after theliquid has been cured, resulting in a lens encapsulating each LED die.

FIG. 4 is a perspective view of an array of LED dice on a submount orcircuit board with a molded lens formed over each LED die.

FIG. 5 is a close-up side view of a flip-chip LED die mounted on asubmount, which is, in turn, mounted on a circuit board, and where amolded lens is formed over the LED die.

FIG. 6 is a close-up side view of a non-flip-chip LED die mounted on asubmount, which is, in turn, mounted on a circuit board, where wireselectrically connect n and p metal on the LED die to leads on thecircuit board, and where a molded lens is formed over the LED die.

FIGS. 7, 8, 9, 10, and 11 are cross-sectional views of an LED die withdifferent lenses formed over it.

FIG. 12 is a cross-sectional view of a side-emitting lens molded ontothe LED die using the inventive techniques.

FIG. 13 is a cross-sectional view of a collimating lens molded onto theLED die using the inventive techniques.

FIG. 14 is a cross-sectional view of a preformed side-emitting lensaffixed over a lambertian lens that has been molded onto the LED dieusing the inventive techniques.

FIG. 15 is a cross-sectional view of a backlight for a liquid crystaldisplay or other type of display using the LED and side-emitting lens ofFIG. 14.

FIG. 16 is a perspective view of a cell phone with a camera that uses asa flash an LED with a molded lens.

FIGS. 17 and 18 are cross-sectional views of two types of molded lenses.All lenses shown are symmetrical about the center axis, although theinvention may apply to non-symmetrical lenses as well.

FIGS. 19-22 illustrate surface features on an inner lens or an outershell lens for obtaining a desired emission pattern.

FIG. 23 illustrates the use of a high domed lens for a collimatedemission pattern.

FIGS. 24 and 25 illustrate the use of a hard outer lens and a soft innerlens to limit the stress on a wire bond.

FIGS. 26-28 illustrate the use of an outer lens formed on various typesof inner or intermediate lenses for a side-emitting pattern.

FIG. 29 illustrates another side-emitting molded lens.

FIG. 30 illustrates the use of molded shells, each containing adifferent phosphor.

FIG. 31 illustrates forming a mold portion on the support substrate forforming a molded lens.

FIG. 32 illustrates depositing a metal reflector over a portion of thelens for achieving a desired emission pattern.

FIG. 33 is a side view of a liquid crystal display using LEDs withside-emitting lenses in a backlight.

FIG. 34 is a side view of a rear projection TV using LEDs withcollimating lenses as a RGB light source.

FIG. 35 illustrates prior art LED emission patterns (Lambertian) andtheir overlapping brightness profiles on a screen.

FIG. 36 illustrates the wide angle emission patterns of LEDs using theinventive lens and their overlapping brightness profiles on a screen.

FIG. 37 shows more detail of the emission pattern of the LEDs in FIG.36.

FIG. 38 is a cross-sectional view of an LED and a wide emitting lens inaccordance with one embodiment of the invention.

FIG. 39 is a graph of light intensity vs. angle for the lens of FIG. 38.

FIG. 40 is a cross-sectional view of an LED and a wide emitting lens inaccordance with another embodiment of the invention.

FIGS. 41A through 41E illustrate steps for overmolding a phosphor wafer,then dicing the molded phosphor wafer and attaching the individualovermolded plates to LED dies.

FIGS. 42A through 42E illustrate steps for overmolding phosphor platesand attaching the overmolded plates to LED dies.

FIGS. 43A through 43D illustrate steps for overmolding an LED with aphosphor plate, where the lens material contains red phosphor to createwarm white light.

FIGS. 44A through 44C illustrate an LED with a flat phosphor layer,where a mold is custom-shaped to form a phosphor-loaded lens thatcompensates for non-uniformity in color vs. angle.

FIGS. 45A and 45B illustrate an LED without a flat phosphor layer, wherea mold is custom-shaped to form a phosphor-loaded lens that improves theuniformity of color vs. angle.

FIGS. 46A through 46D illustrate molding a lens over an LED die andanother type of semiconductor chip, such as a transient voltagesuppressor.

FIGS. 47A through 47C illustrate molding a single lens over multipleLEDs of different colors.

FIGS. 48A through 48C illustrate molding a lens over an LED and thenaffixing a collimating lens on a flat portion of the overmolded lens.

FIGS. 49A and 49B illustrate the use of a silicone gel underfill to fillvoids under an LED die, where the LED is then encapsulated by a hardouter lens.

Elements labeled with the same numeral in the various figures may be thesame or equivalent.

DETAILED DESCRIPTION

As a preliminary matter, a conventional LED is formed on a growthsubstrate. In the example used, the LED is a GaN-based LED, such as anAlInGaN LED, for producing blue or UV light. Typically, a relativelythick n-type GaN layer is grown on a sapphire growth substrate usingconventional techniques. The relatively thick GaN layer typicallyincludes a low temperature nucleation layer and one or more additionallayers so as to provide a low-defect lattice structure for the n-typecladding layer and active layer. One or more n-type cladding layers arethen formed over the thick n-type layer, followed by an active layer,one or more p-type cladding layers, and a p-type contact layer (formetallization).

Various techniques are used to gain electrical access to the n-layers.In a flip-chip example, portions of the p-layers and active layer areetched away to expose an n-layer for metallization. In this way the pcontact and n contact are on the same side of the chip and can bedirectly electrically attached to the package (or submount) contactpads. Current from the n-metal contact initially spreads laterallythrough the n-layer. In contrast, in a vertical injection(non-flip-chip) LED, an n-contact is formed on one side of the chip, anda p-contact is formed on the other side of the chip. Electrical contactto one of the p or n-contacts is typically made with a wire or a metalbridge, and the other contact is directly bonded to a package (orsubmount) contact pad. A flip-chip LED is used in the examples of FIGS.1-3 for simplicity.

Examples of forming LEDs are described in U.S. Pat. Nos. 6,649,440 and6,274,399, both assigned to Philips Lumileds Lighting Company andincorporated by reference.

Optionally, a conductive substrate is bonded to the LED layers(typically to the p-layers) and the sapphire substrate is removed. Oneor more LED dice may be bonded to metal pads on a submount, with theconductive substrate directly bonded to the metal pads, to be describedin greater detail with respect to FIGS. 5 and 6. Electrodes of one ormore submounts may be bonded to a printed circuit board, which containsmetal leads for connection to other LEDs or to a power supply. Thecircuit board may interconnect various LEDs in series and/or parallel.

The particular LEDs formed and whether or not they are mounted on asubmount is not important for purposes of understanding the invention.

FIG. 1 is a side view of four LED dice 10 mounted on a support structure12. The support structure may be a submount (e.g., ceramic or siliconwith metal leads), a metal heat sink, a printed circuit board, or anyother structure. In the present example, the support structure 12 is aceramic submount with metal pads/leads.

A mold 14 has indentations 16 corresponding to the desired shape of alens over each LED die 10. Mold 14 is preferably formed of a metal. Avery thin non-stick film 18, having the general shape of mold 14, isplaced or formed over mold 14. Film 18 is of a well known conventionalmaterial that prevents the sticking of silicone to metal.

Film 18 is not needed if the lens material does not stick to the mold.This may be accomplished by using a non-stick mold coating, using anon-stick mold material, or using a mold process that results in anon-stick interface. Such processes may involve selecting certainprocess temperatures to obtain the minimum stick. By not using film 18,more complex lenses can be formed.

In FIG. 2, the mold indentions 16 have been filled with a heat-curableliquid lens material 20. The lens material 20 may be any suitableoptically transparent material such as silicone, an epoxy, or a hybridsilicone/epoxy. A hybrid may be used to achieve a matching coefficientof thermal expansion (CTE). Silicone and epoxy have a sufficiently highindex of refraction (greater than 1.4) to greatly improve the lightextraction from an AlInGaN or AlInGaP LED as well as act as a lens. Onetype of silicone has an index of refraction of 1.76.

A vacuum seal is created between the periphery of the support structure12 and mold 14, and the two pieces are pressed against each other sothat each LED die 10 is inserted into the liquid lens material 20 andthe lens material 20 is under compression.

The mold is then heated to about 150 degrees centigrade (or othersuitable temperature) for a time to harden the lens material 20.

The support structure 12 is then separated from mold 14. Film 18 causesthe resulting hardened lens to be easily released from mold 14. Film 18is then removed.

In another embodiment, the LED dice 10 in FIG. 1 may be first coveredwith a material, such as silicone or phosphor particles in a binder. Themold indentations 16 are filled with another material. When the dice arethen placed in the mold, the mold material is shaped over the coveringmaterial.

FIG. 3 illustrates the resulting structure with a molded lens 22 overeach LED die 10. In one embodiment, the molded lens is between 1 mm and5 mm in diameter. The lens 22 may be any size or shape.

FIG. 4 is a perspective view of a resulting structure where the supportstructure 12 supports an array of LED dice, each having a molded lens22. The mold used would have a corresponding array of indentations. Ifthe support structure 12 were a ceramic or silicon submount, each LED(with its underlying submount portion) can be separated by sawing orbreaking the submount 12 to form individual LED dice. Alternatively, thesupport structure 12 may be separated/diced to support subgroups of LEDsor may be used without being separated/diced.

The lens 22 not only improves the light extraction from the LED die andrefracts the light to create a desired emission pattern, but the lensalso encapsulates the LED die to protect the die from contaminants, addmechanical strength, and protect any wire bonds.

FIG. 5 is a simplified close-up view of one embodiment of a singleflip-chip LED die 10 on a submount 24 formed of any suitable material,such as a ceramic or silicon. In one embodiment, submount 24 acted asthe support structure 12 in FIGS. 1-4, and the die/submount of FIG. 5was separated from the structure of FIG. 4 by sawing. The LED die 10 ofFIG. 5 has a bottom p-contact layer 26, a p-metal contact 27, p-typelayers 28, a light emitting active layer 30, n-type layers 32, and ann-metal contact 31 contacting the n-type layers 32. Metal pads onsubmount 24 are directly metal-bonded to contacts 27 and 31. Viasthrough submount 24 terminate in metal pads on the bottom surface ofsubmount 24, which are bonded to the metal leads 40 and 44 on a circuitboard 45. The metal leads 40 and 44 are connected to other LEDs or to apower supply. Circuit board 45 may be a metal plate (e.g., aluminum)with the metal leads 40 and 44 overlying an insulating layer. The moldedlens 22, formed using the technique of FIGS. 1-3, encapsulates the LEDdie 10.

The LED die 10 in FIG. 5 may also be a non-flip-chip die, with a wireconnecting the top n-layers 32 to a metal pad on the submount 24. Thelens 22 may encapsulate the wire.

In one embodiment, the circuit board 45 itself may be the supportstructure 12 of FIGS. 1-3. Such an embodiment is shown in FIG. 6. FIG. 6is a simplified close-up view of a non-flip-chip LED die 10 having a topn-metal contact 34 connected to a metal lead 40 on circuit board 45 by awire 38. The LED die 10 is mounted on a submount 36, which in theexample of FIG. 6 is a metal slab. A wire 42 electrically connects thep-layers 26/28 to a metal lead 44 on circuit board 45. The lens 22 isshown completely encapsulating the wires and submount 36; however, inother embodiments the entire submount or the entire wire need not beencapsulated.

A common prior art encapsulation method is to spin on a protectivecoating. However, that encapsulation process is inappropriate for addinga phosphor coating to the LED die since the thickness of the encapsulantover the LED die is uneven. Also, such encapsulation methods do not forma lens. A common technique for providing a phosphor over the LED die isto fill a reflective cup surrounding the LED die with asilicone/phosphor composition. However, that technique forms a phosphorlayer with varying thicknesses and does not form a suitable lens. If alens is desired, additional processes still have to create a plasticmolded lens and affix it over the LED die.

FIGS. 7-11 illustrate various lenses that may be formed using theabove-described techniques.

FIG. 7 illustrates an LED die 10 that has been coated with a phosphor 60using any suitable method. One such method is by electrophoresis,described in U.S. Pat. No. 6,576,488, assigned to Philips LumiledsLighting Company and incorporated herein by reference. Suitablephosphors are well known. A lens 22 is formed using the techniquesdescribed above. The phosphor 60 is energized by the LED emission (e.g.,blue or UV light) and emits light of a different wavelength, such asgreen, yellow, or red. The phosphor emission alone or in conjunctionwith the LED emission may produce white light.

Processes for coating an LED with a phosphor are time-consuming. Toeliminate the process for coating the LED die with a phosphor, thephosphor powder may be mixed with the liquid silicone so as to becomeembedded in the lens 62, shown in FIG. 8.

As shown in FIG. 9, to provide a carefully controlled thickness ofphosphor material over the LED die, an inner lens 64 is formed using theabove-described techniques, and a separate molding step (using a moldwith deeper and wider indentations) is used to form an outerphosphor/silicone shell 66 of any thickness directly over the inner lens64.

FIG. 10 illustrates an outer lens 68 that may be formed over thephosphor/silicone shell 66 using another mold to further shape the beam.

FIG. 11 illustrates shells 70, 72, and 74 of red, green, andblue-emission phosphors, respectively, overlying clear silicone shells76, 78, and 80. In this case, LED die 10 emits UV light, and thecombination of the red, green, and blue emissions produces a whitelight. All shells are produced with the above-described methods.

Many other shapes of lenses can be formed using the molding techniquedescribed above. FIG. 12 is a cross-sectional view of LED 10, submount24, and a molded side-emitting lens 84. In one embodiment, lens 84 isformed of a very flexible material, such as silicone, which flexes as itis removed from the mold. When the lens is not a simple shape, therelease film 18 (FIG. 1) will typically not be used.

FIG. 13 is a cross-sectional view of LED 10, submount 24, and a moldedcollimating lens 86. The lens 86 can be produced using a deformable moldor by using a soft lens material that compresses when being pulled fromthe mold and expands to its molded shape after being released from themold.

FIG. 14 illustrates how a preformed lens 88 can be affixed over a moldedlambertian lens 22. In the example of FIG. 14, lens 22 is formed in thepreviously described manner. Lens 22 serves to encapsulate and protectLED 10 from contaminants. A preformed side-emitting lens 88 is thenaffixed over lens 22 using a UV curable adhesive or a mechanical clamp.This lens-forming technique has advantages over conventional techniques.In a conventional technique, a preformed lens (e.g., a side emittinglens) is adhesively affixed over the LED die, and any gaps are filled inby injecting silicone. The conventional process is difficult to performdue to, among other reasons, carefully positioning the separateddie/submount for the lens placement and gap-filling steps. Using theinventive technique of FIG. 14, a large array of LEDs (FIG. 4) can beencapsulated simultaneously by forming a molded lens over each. Then, apreformed lens 88 can be affixed over each molded lens 22 while the LEDsare still in the array (FIG. 4) or after being separated.

Additionally, the molded lens can be made very small (e.g., 1-2 mmdiameter), unlike a conventional lens. Thus, a very small, fullyencapsulated LED can be formed. Such LEDs can be made to have a very lowprofile, which is beneficial for certain applications.

FIG. 14 also shows a circuit board 45 on which submount 24 is mounted.This circuit board 45 may have mounted on it an array of LEDs/submounts24.

FIG. 15 is a cross-sectional view of a backlight for a liquid crystaldisplay (LCD) or other display that uses a backlight. Common uses arefor televisions, monitors, cellular phones, etc. The LEDs may be red,green, and blue to create white light. The LEDs form a two-dimensionalarray. In the example shown, each LED structure is that shown in FIG.14, but any suitable lens may be used. The bottom and sidewalls 90 ofthe backlight box are preferably coated with a whitereflectively-diffusing material. Directly above each LED is a whitediffuser dot 92 to prevent spots of light from being emitted by thebacklight directly above each LED. The dots 92 are supported by atransparent or diffusing PMMA sheet 94. The light emitted by theside-emitting lenses 88 is mixed in the lower portion of the backlight,then further mixed in the upper portion of the backlight before exitingthe upper diffuser 96. Linear arrays of LEDs may be mounted on narrowcircuit boards 45.

FIG. 16 illustrates an LED 10 with a molded lens 22 being used as aflash in a camera. The camera in FIG. 16 is part of a cellular telephone98. The cellular telephone 98 includes a color screen 100 (which mayhave a backlight using the LEDs described herein) and a keypad 102.

As discussed with respect to FIG. 10, an outer lens may be formed overthe inner shell to further shape the beam. Different shell materials maybe used, depending on the requirements of the various shells. FIGS.17-30 illustrate examples of various lenses and materials that may beused in conjunction with the overmolding process.

FIGS. 17 and 18 illustrate two shapes of molded lenses for an innershell formed using the molding techniques described above. Many LEDs 10may be mounted on the same support structure 12. The support structure12 may be a ceramic or silicon submount with metal traces and contactpads, as previously described. Any number of LEDs may be mounted on thesame support structure 12, and all LEDs on the same support structure 12would typically be processed in an identical manner, although notnecessarily. For example, if the support structure were large and thelight pattern for the entire LED array were specified, each LED lens maydiffer to provide the specified overall light pattern.

An underfill material may be injected to fill any gap between the bottomof the LED die 10 and the support substrate 12 to prevent any air gapsunder the LED and to improve heat conduction, among other things.

FIG. 17 has been described above with respect to FIGS. 3-6, where theinner molded lens 22 is generally hemispherical for a lambertianradiation pattern. The inner molded lens 106 in FIG. 18 is generallyrectangular with rounded edges. Depending on the radiation pattern to beprovided by an outer lens, one of the inner molded lenses 22 or 106 maybe more suitable. Other shapes of inner molded lenses may also besuitable. The top down view of each lens will generally be circular.

FIG. 19 illustrates the structure of FIG. 18 with the lens outer surfacehaving a pattern that refracts light to achieve a desired radiationpattern. The outer surface pattern may be directly formed in the innermolded lens (by the mold itself), or the outer surface pattern may beformed in an outer lens that is overmolded onto the inner molded lens oris affixed to it by an adhesive (e.g., silicone, epoxy, etc.). Pattern108 is a diffraction grating, while pattern 110 uses binary steps torefract the light. In the examples, the pattern forms a generallyside-emitting lens with the radiation pattern shown in FIG. 20. In FIG.20, the peak intensity occurs within 50-80 degrees and is significantlygreater than the intensity at 0 degrees.

The requirements for the inner lens are generally different from therequirements for the outer lens. For example, the inner lens should havegood adhesion to the support structure, not yellow or become more opaqueover time, have a high index of refraction (greater than 1.4), not breakor stress any wires to the LED, withstand the high LED temperatures, andhave a compatible thermal coefficient. The inner lens should benon-rigid (e.g., silicone) to not provide stress on the LED or anywires. In contrast, the outer lens material generally only needs to beable to be patterned with the desired pattern and adhere to the innerlens. The outer lens may overmolded or may be preformed and adhesivelyaffixed to the inner lens. The material for the outer lens may be UVcurable, while the material for the inner lens may be thermally cured.Thermal curing takes longer than UV curing.

Generally, the range of hardness for the inner lens material is Shore 005-90, while the range of hardness for the outer shell(s) is Shore A 30or more.

FIG. 21 illustrates a Fresnel lens pattern 112 formed on the outersurface of the lens for creating a generally side-emitting light patternsimilar to that of FIG. 20. The outer surface may be the outer surfaceof the inner molded lens or the outer surface of an outer shell, asdescribed with respect to FIG. 19. This applies to all patternsdescribed herein.

FIG. 22 illustrates pyramid 114 or cone shaped 116 patterns on the outerlens surface to create a collimating light pattern or another lightpattern.

FIG. 23 illustrates a high dome outer lens 118 for creating acollimating pattern.

The surface patterns of FIGS. 19 and 21-23 may be configured (e.g., bychanging the surface angles) to create any light pattern. Holographicstructures, TIR, and other patterns may be formed. Collimating lightpatterns are typically used for rear projection TVs, while side-emittinglight patterns are typically used for backlighting LCD screens.

FIG. 24 illustrates the use of a soft material, such as a silicone gel,as the inner molded lens 124 so as to not stress the wire 126 bonded tothe LED 10. The gel is typically UV cured. The outer lens 128 may bemolded or preformed and affixed with an adhesive. The outer lens 128will typically be much harder for durability, resistance to particles,etc. The outer lens 128 may be silicone, epoxy-silicone, epoxy, siliconeelastomers, hard rubber, other polymers, or other material. The outerlens may be UV or thermally cured.

FIG. 25 is similar to FIG. 24 but with a different shaped inner moldedlens 129 (like FIG. 18) for a different emission pattern or a lowerprofile. Lens 129 may be a soft silicone gel. The outer lens 130 willfurther shape the emission pattern and protect the soft inner lens 129.

The LEDs in all figures may be flip-chips or wire bonded types.

FIG. 26 illustrates an LED structure with a soft inner molded lens 132,having the properties needed for the inner lens, a hard intermediateshell 134 to act as an interface layer and for structural stability, andan outer lens 136 for creating a side-emitting light pattern. The outerlens 136 may be soft to facilitate the molding process. Alternatively,the outer lens 136 may be preformed and adhesively affixed to theintermediate shell 134. The use of the intermediate shell 134 makes thechoice of the outer lens material essentially independent of the innerlens material.

FIG. 27 illustrates how the outer lens 138 may be formed on any portionof the intermediate shell 134 or inner lens 132.

FIG. 28 illustrates the formation of the outer lens 142 directly on theinner lens 144 material.

FIG. 29 illustrates another shape of side-emitting lens 145 molded overan inner lens 132. Lens 145 may be directly molded over LED die 10without any inner lens.

FIG. 30 illustrates an LED where each shell 146, 147, and 148 contains adifferent phosphor material, such as a red-emitting phosphor, agreen-emitting phosphor, and a blue-emitting phosphor. The LED die 10may emit UV. The gaps between phosphor particles allow the UV to passthrough an inner shell to energize the phosphor in an outer shell.Alternatively, only red and green phosphor shells are used, and the LEDdie 10 emits blue light. The combination of red, green, and blue lightcreate white light. The thickness of the shells, the density of thephosphor particles, and the order of the phosphor colors, among otherthings, can be adjusted to obtain the desired light. Any shape of lensesmay be used.

FIG. 31 illustrates the use of a mold pattern 149 on the supportstructure 12 itself. A high index material (e.g., a polymer) or areflective material (e.g., aluminum or silver) is formed by eithermolding the pattern on the support structure 12, using a method similarto the method shown in FIG. 1, or using a metallization process, orusing another suitable process. The mold pattern 149 is then used as amold for another material forming a lens 150. In one embodiment, thelens 150 material is a liquid (e.g., silicone) that is deposited in themold formed on the support structure 12, then cured. The surface maythen be planarized. The resulting lens collimates the light byreflecting/refracting the light impinging on the walls like a reflectorcup.

FIG. 32 illustrates a molded lens 22 with metal 151 sputtered around itsside to reflect light emitted by the LED 10. The reflected light will bescattered by the LED 10 and be eventually emitted through the topopening. The metal 151 may be any reflective material such as aluminumor silver. The metal may instead be sputtered on the top of the lens 22to create a side-emission pattern. The lens 22 may be made any shape tocreate the desired light emission pattern.

FIG. 33 is a side view of a liquid crystal display (LCD) 152 with an LCDscreen 154, having controllable RGB pixels, a diffuser 156, and abacklight 158 for mixing light from red, green, and blue LEDs 160 tocreate white light. The backlight 158 is a diffusively reflective box.The LEDs 160 have side-emitting lenses made using any of theabove-described techniques.

FIG. 34 is a side view of a rear projection television 162 with a frontlens 164 for brightening the image within a specified viewing angle, aset of red, green, and blue LEDs 166, modulator/optics 170 formodulating and focusing the RGB light to produce a color TV image, and areflector 172. The modulator may be an array of controllable mirrors, anLCD panel, or any other suitable device. The LEDs 166 have collimatinglenses made using any of the above-described techniques.

As described above, the primary lens or secondary lens can be designedto create a side-emitting pattern. Such a side emitting pattern isparticularly useful when light from multiple LEDs is intended to bemixed, such as when light from multiple LEDs is for creating a uniformbacklight for an LCD panel, or for decorative lighting, or for anotheruse.

As shown in FIG. 35, LEDs 180, without lenses or with only hemisphericallenses, mounted on a backplane 182 will typically emit light in aLambertian pattern 183. The array of LEDs 180 illuminates the back of adiffusive screen 184. The screen 184 may be the diffuser 156 in the LCDbacklight of FIG. 33. The diffused brightness profile 185 of each LEDand its Full Width At Half Maximum (FWHM) are also shown. The overalllight output at the front of the screen 184 will have noticeable brightspots unless the LEDs are placed close enough together. Therefore, sucha backlight requires a relatively high density of LEDs, resulting in anexpensive backlight.

Applicants have invented a wide-emitting lens, shown in FIGS. 36-38,that is particularly useful in a backlight. In FIG. 36, LEDs 188 withthe wide-emitting lenses are shown mounted to a backplane 190. The peaklight emission (Ipeak) for each LED die occurs within 50-80 degrees offthe center axis (normal), as shown in FIG. 37. A range between 70-80degrees is preferred. The lens is designed so that the light emission(I₀) along the center axis is 5%-33% of the peak emission. Accordingly,the brightness profile 192 for each LED is more spread out as comparedto the brightness profile 185 in FIG. 35. Therefore, the LED 188 pitchin the backlight of FIG. 36 can be larger than the LED 180 pitch in FIG.35 while achieving the same light output uniformity from the diffusivescreen 184. This results in a less expensive backlight.

The brightness profile should have no sharp transitions like those thattypically appear with funnel shaped lenses at the center cusp.

The optimum ratio of the center axis intensity to the 50-80 degree peakintensity will depend on the application, such as the pitch of the LEDsneeded to achieve the specified brightness of the backlight. The peakintensity is at least three times the intensity along the center axisand, in the embodiment of FIG. 37, the ratio is between 4-8.

FIG. 38 is a cross-sectional view of one embodiment of a wide-emittinglens with the characteristics described above. An LED die 194 is mountedon a substrate or submount 196 made of ceramic, silicon, or othermaterial, as described with respect to FIGS. 1-6, and a first lens 198is molded over the LED die 194 as described with respect to FIGS. 1-6.Multiple dies may be mounted on a single large submount. Lens 198 may beformed of any suitable material such as silicone.

The submount 196 is then separated out and then mounted on a backplane190 (a PCB) by a solder reflow technique or other suitable technique.

A secondary lens 202 is preformed to have the desired wide-emittingcharacteristics. The secondary lens may be injection-molded or machinedplastic or other material. Such materials include COC, COP, PMMA, epoxy,silicone, glass, or any other suitable material. The secondary lens 202is then mounted to overlie the first lens 198 and contact the backplane190 for support. An air gap 204 (or other low index of refractionmaterial gap) creates an internal refractive interface that bends lighttowards the sides. The interface of the outer surface of the secondarylens 202 with air further bends the light to achieve the peak intensitywithin 50-80 degrees. The secondary lens 202 may directly contact thefirst lens 198; however, the shape of the secondary lens 202 would haveto be changed to achieve the same wide-emitting pattern.

In another embodiment, the secondary lens 202 contacts and is supportedby the submount 196 rather than the backplane 190.

The secondary lens 202 may be fixed to the backplane or the submountwith an adhesive such as epoxy or may be affixed with a snap-tabconnection.

By fixing the secondary lens 202 referenced to the submount, slightlybetter control over the light emission is achieved as compared to fixingthe secondary lens 202 referenced to the backplane because the height ofthe LED and first lens 198 above the backplane may vary slightly withthe mounting parameters.

The aspherical secondary lens 202 with the aspherical dome internal airgap is a simple design that is easily molded. The lens 202 is undercutnear the backplane 190 to reflect light upward at the undercut surfaceso that light is not emitted downward toward the backplane 190. Thisavoids light rings and increases the backlight's light output.

FIG. 39 shows the light intensity vs. angle for the LED of FIG. 38. Thepeak intensity is approximately 72 degrees, and the intensity along thecenter axis is approximately 10% of the peak intensity.

In another embodiment, the surface of the secondary lens 202 containsmicrostructures, as described with respect to FIGS. 19, 21, and 22, thatfurther refract the light to achieve the desired emission pattern.

FIG. 40 is a cross-sectional view of an LED 194 with a lens 206 that hasa total internal reflection (TIR) portion 208. The TIR portion 208 isfunnel-shaped. The TIR portion 208 causes most light emitted upward tobe internally reflected and emitted through the side portions 210. Sucha design is useful to reduce the intensity along the central axis whilestill providing a peak intensity within 50-80 degrees and an intensityalong the central axis between 5-33% of the peak intensity. Any of thelens embodiments may be employed in the backlight of FIG. 33.

The secondary lenses in FIGS. 38 and 40 and in other figures may also beused over an LED die without a molded first lens. However, use with themolded first lens is preferable to protect the LED. The diameter of thesecondary lens will typically range between 4-10 mm.

FIGS. 41A through 41E illustrate steps for overmolding a ceramicphosphor plate and attaching the overmolded plate to an LED die. Aphosphor plate can be made to have precise characteristics since itsthickness (e.g., 50-300 microns) and phosphor density can be carefullycontrolled. When the phosphor is energized by blue light (e.g., 440nm-460 nm), the phosphor emits a longer wavelength light. When thephosphor plate is affixed over a blue LED, a percentage of the bluelight passes through the plate, and the blue light is mixed with thelight generated by the phosphor.

One way to form a sheet of ceramic phosphor is to sinter grains of thephosphor powder using heat and pressure. The percentage of the blue LEDlight passing through the plate is dependent on the density of thephosphor and the thickness of the plate, which can be preciselycontrolled. Another way to form a thin sheet of phosphor is to form aslurry of phosphor in a thin sheet and then dry the slurry. Forming suchceramic phosphor plates is described in U.S. patent publication20050269582, entitled Luminescent Ceramic for a Light Emitting Diode, byGerd Mueller et al., incorporated herein by reference.

A popular phosphor to use with a blue LED is a YAG:Ce phosphor (YttriumAluminum Garnet doped with about 2% Cerium), which is commerciallyavailable.

FIG. 41A illustrates a ceramic phosphor plate wafer 211 temporarilymounted on a backplate 212 using any suitable adhesive that can beeasily released with force or with a solvent. The backplate 212 may havea Teflon coating that prevents sticking of cured silicone in a laterstep. The wafer is typically rectangular but can be any shape. The waferwill later be sawed to form phosphor plates for hundreds of LEDs. Inthis example, the wafer 211 is a YAG phosphor 50-300 microns thick,which emits a green-yellow light when energized with blue light from ablue LED. The resulting white light is generally considered harsh sinceit has a high color temperature (e.g., 4000-6000K). As described below,red phosphor will be used to lower the color temperature, which isconventionally referred to as creating a warmer white light.

In FIG. 41B, an indention 213 in a mold 214 is filled with liquidsilicone 215 containing red phosphor particles 216. A conventionalnon-stick release film (not shown) conformally coats the mold and laterenables the molded silicone to be removed without significant pull. Anytype of automated liquid dispenser can be used to dispense thesilicone/phosphor mixture. Examples of red phosphor include BaSSN, CaS,and e-CaS, which are well known. The optimal density of the red phosphorparticles and shape of the indentation 213 are determined by the desiredlowering of the color temperature provided by the red phosphor. Otherphosphor particles, such as YAG, green, orange, blue, etc., may also bein the silicone 215 if desired to achieve a certain color temperature.In one embodiment, the silicone 215 used is such that it is relativelysoft after curing so that there is little stress on the LED andresulting phosphor plate during operation of the LED structure. Inanother embodiment, the silicone 215 is the same or equivalent to thesilicone later used to form the outer lens.

The backplate 212 and the mold 214 are then brought together so as toimmerse the phosphor wafer 211 into the silicone 215. The backplate 212and mold 214 are clamped together, a vacuum is created around thestructure, and the silicone 215 is under compression. Any air bubbles inthe liquid silicone are evacuated during this overmolding step. Thesilicone 215 is then cured by heat or UV. The backplate 212 and mold 214are then separated, aided by the release film.

The resulting molded phosphor wafer is then sawed to form individualmolded phosphor plates, where each plate is approximately the size of anLED. The phosphor-loaded silicone forms a lens over the phosphor plate.In one embodiment, the molded phosphor wafer is retained on thebackplate 212 during the sawing process, and the saw blade only cutsthrough the wafer. This makes the plates easier to pick and place by anautomated pick and place machine. In another embodiment, the moldedwafer is removed from the backplate 212, then sawed.

In FIG. 41C, an automatic pick and place arm removes each moldedphosphor plate 218 (YAG plate 220 with phosphor-loaded silicone 221)from the backplate 212 and adheres the molded phosphor plate 218 to thetop surface of a blue LED 224 mounted on a submount 226 (a wafer at thisstage). The submount 226 may contain hundreds of blue LEDs 224 in atwo-dimensional array similar to the array shown in FIG. 4. The submount226 is typically ceramic and contains metal traces and electrodes foreach LED for attachment to a power supply. The adhesion of the phosphorplate 218 to the LED 224 may be by low-melting-temperature glass,silicone, epoxy, other transparent adhesive, or heat and pressure.

In one embodiment, to be elaborated on later, the shape of the moldindention 213 is determined by computer modeling to compensate for thenon-uniformity of the color temperature vs. angle of the light emittedby the LED/plate combination.

In FIG. 41D, a clear silicone lens 234 is molded over the LED 224 andmolded phosphor plate 218 to encapsulate the entire structure. Theprocess described with respect to FIGS. 1-4 and other figures may beused to form the outer lens 234. The molded outer lens 234 improves thelight extraction of the LED, achieves a desired light emission pattern,and prevents the phosphor plate 218 from delaminating.

In another embodiment, the outer lens 234 is harder than thephosphor-loaded silicone 221. This results in a mechanically strongouter lens for protection as well as a smooth outer surface that isresistant to dust particles while reducing stress on the LED andinterconnections.

The submount 226 is then diced to singulate the LED structures. The LEDsin the above example emit a warm white light, such as within 3000-4000K.Any other phosphors can be used for the phosphor plate and the phosphorin the silicone.

The color temperatures can be further controlled by binning the moldedphosphor plates 218 in accordance with their color characteristics aftera test. The LEDs 224 on the submount 226 are then tested and categorizedin accordance to their color characteristics. The binned molded phosphorplates 218 are then selected for a particular LED to achieve a targetcolor temperature.

FIG. 41E illustrates another embodiment of the overmolded phosphor plate218 affixed to an LED 224. In FIG. 41E, the molded phosphor plates 218are affixed to the LEDs 224 silicone-side down using silicone or heat.

FIGS. 42A through 42E are similar to FIGS. 41A through 41E except thatthe phosphor plates are diced before being molded. The phosphor sheet isfirst sawed or broken to create phosphor plates approximately the samesize as the energizing LED.

FIG. 42A illustrates a two-dimensional array of ceramic phosphor plates228 being temporarily mounted on a backplate 222 using any suitableadhesive that can be easily released with force or with a solvent. Thebackplate 222 and phosphor plate characteristics may be the same as inFIGS. 41A-41E.

In FIG. 42B, indentions 229 in a mold 230 are filled with liquidsilicone 231 containing red phosphor particles 232. A conventionalnon-stick release film (not shown) conformally coats the mold and laterenables the molded silicone to be removed without significant pull. Thecharacteristics of the phosphors, silicone, and mold are similar tothose described above.

The backplate 222 and the mold 230 are then brought together so as toimmerse the plates 228 into the silicone 231. The backplate 222 and mold230 are clamped together, a vacuum is created around the structure, andthe silicone 231 is under compression. The silicone 231 is then cured byheat or UV. The backplate 222 and mold 230 are then separated, aided bythe release film.

In FIG. 42C, an automatic pick and place arm removes each molded plate234 from the backplate 222 and adheres the molded plate 234 to the topsurface of a blue LED 236 mounted on a submount wafer 238. The submount238 may contain hundreds of blue LEDs 236 in a two-dimensional arraysimilar to the array shown in FIG. 4. The submount 238 is typicallyceramic and contains metal traces and electrodes for each LED forattachment to a power supply. The adhesion of the phosphor plate 228 tothe LED 236 may be by low-melting-temperature glass, silicone, epoxy,other transparent adhesive, or heat and pressure.

In one embodiment, to be elaborated on later, the shape of the moldindentions 229 is determined by computer modeling to compensate for thenon-uniformity of the color temperature vs. angle of the light emittedby the LED/plate combination.

In FIG. 42D, a clear silicone lens 244 is molded over the LED 236 andmolded plate 234 to encapsulate the entire structure. The processdescribed with respect to FIGS. 1-4 and other figures may be used toform the outer lens 244.

The submount 238 is then diced to singulate the LED structures. The LEDsin the above example emit a warm white light, such as within 3000-4000K.Any other phosphors can be used for the phosphor plate and the phosphorin the silicone. The advantages of binning and matching were describedwith respect to FIGS. 41A-41E.

FIG. 42E illustrates another embodiment of the overmolded phosphor plate234 affixed to an LED die. In FIG. 42E, the molded plates 234 areaffixed to the LEDs 236 lens-side down using silicone or heat. Tosimplify the pick-and-place process, the backplate 222 (FIG. 42B) may bereleased from the molded plates while the molded plates are still in themold 230. The pick-and place arm then attaches to the exposed plate,removes the molded plate from the mold 230, and places it on the LED236.

In FIGS. 41A-E and 42A-E, the first molding step only covers thephosphor plates. FIGS. 43A through 43D show a process where the firstmolding step also encapsulates the LED.

In FIG. 43A, the phosphor plates 228 (e.g., YAG) are affixed to the LEDdies 236 on the submount 238.

In FIG. 43B, indentions 248 in a mold 250 are filled with liquidsilicone 252 containing red phosphor particles 254. As mentioned above,other phosphors may also be used. The submount 238 and mold 250 arebrought together, and the silicone 252 is heated to cure it. Theresulting silicone may be relatively soft for reasons stated above ormay be the same or similar to the silicone used to form the outer lens.

In FIG. 43C, the submount 238 and mold 250 are separated so that a redphosphor lens 258 encapsulates each LED and phosphor plate, creating awarm white light.

In FIG. 43D, a hard silicone lens 260 is molded over the each LED, usingthe molding processes described herein, to encapsulate and protect theentire LED structure. As in all embodiments, the outer lens 260 may beshaped by the mold to create virtually any light emission pattern, suchas lambertian, side-emitting, collimated, etc.

FIGS. 44A through 44C illustrate the use of the molding process tocreate a more uniform color temperature vs. viewing angle.

In FIG. 44A, a YAG phosphor 262 powder conformally coats the LED 236,resulting in a flat phosphor surface. One way to conformally coat an LEDwith phosphor is by electrophoretic deposition. Electrophoreticdeposition is described in U.S. Pat. No. 6,576,488, entitled “UsingElectrophoresis to Produce a Conformally Coated Phosphor-Converted LightEmitting Semiconductor,” by Dave Collins et al., incorporated herein byreference. The process of FIGS. 44B and 44C also applies when thephosphor is a plate, such as shown in FIG. 43A. The process of FIGS. 44Band 44C also applies to any LED structure where the color temperaturevs. angle is desired to be more uniform.

The color temperature graph shown in FIG. 44A indicates that the colortemperature of the phosphor-coated LED at a 0% viewing angle is cooler(higher CCT or bluer) than at other viewing angles. This is because theblue light travels the least distance through the phosphor whentraveling normal to the surface. As a result, the white light changescolor as the LED is viewed from different angles. Although the range ofcolor temperatures shown is from 3000K to 3500K, the temperatures may behigher (e.g., up to 6000K) or lower depending on the particular phosphorand thickness of the coating.

It would be very difficult to precisely form a phosphor coating thatvaries in thickness so that the blue light travels the same distancethrough the phosphor at all angles.

To compensate for this color vs. angle non-uniformity, a molded lenscontaining a substantially homogenous distribution of a compensatingphosphor is used. In one example, a red phosphor is dispersed in liquidsilicone in a mold, similar to mold 250 in FIG. 43B. The dimensions ofthe mold are determined by computer modeling based on the actual colortemperature vs. angle characteristics of the LED to be corrected.Generally, the mold will be convex, where the precise width, depth,curvature, and phosphor density are determined by the computer modeling.The LED with the phosphor coating is placed into the liquid silicone,and the silicone is cured. The LED with the molded lens is then removedfrom the mold.

FIG. 44B illustrates one example of the compensating molded lenses 264containing the red phosphor. Other compensating phosphors may be used,depending on the desired color temperature. As seen by the graph ofcolor temperature vs. angle, the average temperature is lowered by theadded red component from the red phosphor, and the temperature delta islowered from 500K (from FIG. 44A) to 250K, creating a more uniform colortemperature vs. angle. Lens 264 is preferable relatively soft to reducestress on the LED.

In FIG. 44C, a hard silicone lens 268 is molded over the colorcompensating lens 264 using previously-described techniques.

FIG. 45A illustrates an LED 236 without a flat phosphor layer, where amold is custom-shaped to form a phosphor-loaded lens 272 that improvesthe uniformity of color temperature vs. angle. Computer modeling is usedto determine the optimum shape of the mold and the phosphor densitybased on the color vs. angle of the LED. Generally, the shape of thelens 272 causes the blue light to travel through approximately the samethickness of the lens over a wide range of angles. The relative size ofthe lens would be much larger than shown in FIG. 45A. The phosphor inthe lens 272 may be a combination of YAG and red or any other phosphor.The phosphor distribution in the lens is substantially homogenous.Multiple overlapping molded lenses may also be used to achieve thedesired color characteristics.

A hard outer lens 276 is then molded over the softer compensating lens272. The lens 276 may be clear or contain a phosphor.

In FIG. 45B, the inner molded lens 272 contains YAG phosphor, anintermediate molded lens 277 contains red phosphor, and a hard outerlens 276 contains no phosphor. Both of lenses 272 and 277 can be shapedto provide a substantially uniform color temperature vs. angle. Othertypes of phosphors and additional phosphor-loaded lenses may also beused. In some cases, better control over the color and color temperaturevs. angle is provided by not mixing all the phosphors into a singlelens. A clear outer lens generally increases the light extraction.

FIGS. 46A through 46D illustrate molding lenses over an LED die andanother type of semiconductor chip, such as a transient voltagesuppressor (TVS) or a photodetector.

FIG. 46A is a top down view of a portion of a submount 280 showing anLED 282 and a TVS chip 284 connected between the power leads of the LED282. The metal traces on the submount 280 are not shown. Upon a voltagesurge, such as due to an electrostatic discharge (ESD), the circuit inthe TVS chip 284 shorts the transient voltage to ground to bypass theLED 282. Otherwise, the LED 282 may be damaged. TVS circuits are wellknown. To Applicants' knowledge, prior art TVS circuits are notencapsulated with a portion of the lens used for the LED. The submount280 shown in FIG. 46A is part of a wafer on which is mounted manypairings of LEDs and TVS dies. The submount wafer will be later sawed tosingulate the LED/TVS pairs.

FIG. 46B is a side view of the submount 280. A mold, similar to thatshown in FIG. 43B and other figures, has indentations that are filledwith liquid silicone containing phosphor grains. The submount wafer andmold are brought together so that each LED/TVS pair is within thesilicone in a single indentation, and the silicone is then cured. Thesubmount wafer is then separated from the mold, and the structure ofFIG. 46C results. The molded phosphor lens 286 encapsulates both chips.The type(s) of phosphor used, the density of the phosphor(s), and theshape of the lens 286 are determined by the desired color temperaturecharacteristics. In one embodiment, the phosphor in the lens 286 is amixture of YAG and red phosphor to create a warm white light whenenergized by the blue LED 282.

As shown in FIG. 46D, a second overmolding process is performed, similarto the processes previously shown, to form a clear silicone lens 288over the molded phosphor lens 286. As with the other embodiment, theinner lens 286 is preferably softer than the outer lens 288. The outerlens 288 is shaped to provide the desired refraction of the light toachieve virtually any emission pattern and also completely encapsulatesthe chips. The portion of the outer lens 288 over the TVS chip 284 haslittle effect on the light emission pattern of the LED. In an actualembodiment, the thickness of the two chips is typically much smallerrelative to the height of the outer lens than shown in FIG. 46D. Forexample, the thickness of the LED 282 may be 120 microns (with itsgrowth substrate removed), the molded phosphor lens 286 may have athickness of 100 microns over the LED, and the outer lens 288 may have athickness of 1000 microns over the molded phosphor lens 286.

The footprint of the molded phosphor lens 286 need not be rounded likethe footprint of a hemispherical outer lens. The footprint of thephosphor lens 286 may be rectilinear to just cover the LED and TVS pair.

As in all embodiments, the outer lens may contain one or more phosphortypes to achieve any color temperature, such as warm white.

Although an outer silicone lens may be simply molded over an innersilicone lens, it has been discovered that an intermediate plasmatreatment of the inner lens increases the adhesion between the twolenses. The plasma treatment slightly etches and roughens the lens.Subjecting the inner lens to a plasma power of 200 Watts for a fewminutes (e.g., 2-15 minutes) is sufficient to ensure the adhesionbetween the two silicone lenses is greater than the adhesion of theouter lens to the mold release film. The plasma power may beapproximately 200-600 Watts. The plasma gas may be any suitable inertgas, such as argon, and the process may be performed in any suitablechamber that can create a plasma. FIG. 43C illustrates the optionalplasma 289 step. The plasma step may be performed in any embodimentwhere two or more overmolded lenses are formed. Providing a clearsilicone lens as an outer lens has been shown to increase the lightoutput power by 24% due to its index of refraction being lower than theindex of refraction of phosphor-loaded silicone.

In FIGS. 46A-46D, the LED may be any color such as blue, cyan, green,etc., and multiple LEDs may be overmolded with a non-LED chip.

FIGS. 47A through 47C illustrate molding a single lens over multipleLEDs of different colors. FIG. 47A is a top down view of a portion of asubmount 290 containing a red LED 292, a green LED 293, and a blue LED294. The metal traces are not shown. The submount wafer contains manysuch groups, each group creating white light having any desired colortemperature depending on the relative brightness levels of the RGB LEDs.

The arrangement, colors, and ratio of each color are not limited. Forexample, the group of LEDs could also include a white LED, or the groupcould include 2-3 red LEDs by themselves or along with one or more greenand blue LEDS, or the group may be 2 white LEDs plus an amber LED.

In FIG. 47B, a mold 296 has indentations 297 filled with liquid silicone298 for forming a single lens over each group of RGB LEDs on thesubmount wafer. The submount 290 is clamped against the mold 296, andthe silicone is cured.

In FIG. 47C, the submount wafer and mold 296 are then separated to forma molded lens 300 over the group of LEDs. In one embodiment, the lens300 contains one or more phosphors. The submount wafer is thensingulated or the entire submount wafer may form an LED display unit.Any number and colors of the LEDs may be encapsulated by a singleovermolded lens.

FIGS. 48A through 48C illustrate overmolding a lens on an LED and thenaffixing a collimating lens on a flat portion of the overmolded lens.

In FIG. 48A, a submount wafer 310 has mounted on it an array of LEDs312. Bottom electrodes of each LED die are ultrasonically bonded tometal contact pads on the submount using gold balls 314. Other bondingtechniques can also be used. The submount wafer 310 is then clamped to amold with each LED being within a mold indentation previously filledwith liquid silicone. The indentations are in the shape of the moldedsilicone lenses 316 shown in FIG. 48A. The silicone is then cured. Thesubmount wafer 310 is then separated from the mold. Each molded lens 316encapsulates an LED and has a flat top portion.

A preformed Fresnel lens 318 is then affixed to the flat portion of themolded lens 316 by silicone glue 319, epoxy, or by other means. TheFresnel lens 318 has very fine features that collimate the light. Thereason why the Fresnel lens cannot be directly formed in the molded lens316 by a pattern in the mold is that the release film (which forms a 50micron layer over the mold) cannot contour to such fine patterns in themold. If the mold is formed of a non-stick substance and the releaselayer is not needed, then a Fresnel lens may be directly molded into thelens. The separate Fresnel lens 318 may be formed by stamping a softenedplastic material or using other means. In one embodiment, the Fresnellens 318 has a circular footprint.

A wall portion 320 of the molded lens 316 surrounds each Fresnel lens318 and is approximately the same height as the Fresnel lens 318. Thiswall portion 320 has angled sides that reflect upward any light emittedfrom the sides of the Fresnel lens 318. Additionally, the wall portion320 protects the Fresnel lens 318 from being bumped. Providing themolded lens with wall portions is optional, and the molded lens can beany shape that supports another lens on top.

The submount wafer 310 is then sawed along the saw lines 322 tosingulated the collimated light sources. In one embodiment, the lightsources of FIGS. 48A-C are used as a miniature flash for the cell phonecamera of FIG. 16. Other types of collimating lenses may be used.

The molded lens may also contain phosphor, as shown in FIG. 48B. In FIG.48B, the LED emits blue light and different types of phosphors 326, 328are dispersed in the liquid silicone when molding the lens 330. In oneembodiment, the phosphors provide at least red and green components tothe blue light to create white light. In one embodiment, the phosphorsinclude a YAG phosphor and a red phosphor for warm white light.

FIG. 48C illustrates an embodiment where the blue LED 312 is conformallycoated with a phosphor 334, such as YAG. The coating may be done usingelectrophoresis. The molded silicone lens 336 contains a red phosphor338 to produce a warm white light.

FIGS. 49A and 49B illustrate the use of a silicone gel underfill to fillvoids under an AlInGaN LED die, where the LED is then encapsulated by ahard outer lens. In FIG. 49A, an LED 340, with its growth substrate(e.g., sapphire) facing upward, is mounted on a submount 342 so thatmetal contacts 344 on the LED 340 are bonded to metal traces 346 on thesubmount 342. The metal traces terminate in wire bond pads or surfacemount pads on the bottom of the submount 342. An underfill material 348,such as a silicone gel, is then injected under the LED 340 to fill thevoids created between the LED 340 and the submount 342. The gel is thencured. The cured gel remains relatively soft.

An excimer laser beam is then applied to the transparent growthsubstrate, which heats the GaN LED surface and disassociates the GaN atthe surface to create gallium and nitrogen gas. The nitrogen expands tolift the sapphire substrate off the GaN LED, and the sapphire substrateis removed. Tremendous downward pressure is created during this process,and the underfill 348 mechanically supports the thin LED layers toprevent breakage of the LED. The underfill 348 also helps to conductheat from the LED to the submount during operation of the LED.

A hard silicone lens 350, either clear or phosphor-loaded, is thenmolded over the LED using the techniques described herein. The underfill348 prevents the liquid outer lens material in the mold from enteringthe voids. This reduces the thermal stress on the LED during operation,which otherwise may result in the LED lifting off from the submount. Theunderfill can be optimized to perform its function without concern overits optical properties.

FIG. 49B illustrates an embodiment where the sapphire growth substrate354 is left on the LED layers. The underfill 356 may be deposited alongthe sides of the LED 340 and substrate 354 to ensure all voids arefilled and to reduce pressure between the LED/substrate and the hardouter molded lens 358 when the LED is heated and cooled duringoperation. Further, if the underfill is not transparent, the underfillalong the sides blocks the side emission, which is advantageous if aphosphor layer is over the top of the substrate. As in all embodiments,the outer lens may be phosphor-loaded.

In all embodiments described herein, an underfill silicone gel may beemployed. Further, an LED emitting UV light may be used in place of theblue LEDs described herein, and a blue phosphor may be dispersed in amolded lens.

While particular embodiments of the present invention have been shownand described, it will be obvious to those skilled in the art thatchanges and modifications may be made without departing from thisinvention in its broader aspects and, therefore, the appended claims areto encompass within their scope all such changes and modifications asfall within the true spirit and scope of this invention.

1-12. (canceled)
 13. A light emitting diode (LED) structure comprising:an LED emitting blue light or UV light on a submount; a substantiallyflat phosphor layer overlying the LED; a molded phosphor-loaded lensover the phosphor layer; and a clear lens, containing no phosphor,molded over the LED and phosphor-loaded lens.
 14. The structure of claim13 wherein the phosphor layer is a phosphor plate that is affixed to theLED.
 15. The structure of claim 13 wherein the phosphor-loaded lens isaffixed to the LED with the phosphor layer adjacent the LED.
 16. Thestructure of claim 13 wherein the phosphor layer contains YAG phosphorand the phosphor in the phosphor-load lens comprises red phosphor. 17.The structure of claim 13 wherein the LED in combination with thephosphor layer has a color temperature vs. viewing angle, and whereinthe phosphor-loaded lens is shaped to increase uniformity of the colortemperature vs. viewing angle.
 18. The structure of claim 13 wherein thephosphor layer is a phosphor layer conformally coating the LED.
 19. Thestructure of claim 13 wherein the combination of light from the LED, thephosphor layer, and the phosphor-loaded lens produces white light.20-22. (canceled)
 23. A light emitting diode (LED) structure comprising:an LED emitting blue light or UV light on a submount; a molded firstphosphor-loaded lens containing a first phosphor over the LED; a moldedsecond phosphor-loaded lens containing a second phosphor over the firstphosphor-loaded lens; a molded clear lens, containing no phosphor overthe second phosphor-loaded lens.
 24. The structure of claim 23 whereinthe first phosphor is different from the second phosphor.
 25. Thestructure of claim 23 wherein the LED in combination with the firstphosphor-loaded lens has a color temperature vs. viewing angle, andwherein the second phosphor-loaded lens is shaped to increase uniformityof the color temperature vs. viewing angle.
 26. A light emitting diode(LED) structure comprising: an LED on a submount along with one or moresemiconductor dice mounted on the submount; and a single lens moldedover the LED and the one or more semiconductor dice.
 27. The structureof claim 26 further comprising a molded phosphor-loaded lens overlyingthe LED and the one or more semiconductor dice, where the single lens ismolded over the phosphor-loaded lens.
 28. The structure of claim 26wherein the one or more semiconductor dice comprise one or more LEDs.29. The structure of claim 26 wherein the one or more semiconductor dicecomprise a plurality of LEDs emitting different colors.
 30. Thestructure of claim 26 wherein the one or more semiconductor dicecomprise a transient voltage suppressor.
 31. The structure of claim 26wherein the one or more semiconductor dice comprise a photodetector. 32.The structure of claim 26 wherein the single lens molded over the LEDand the one or more semiconductor dice is not symmetrical about acentral axis.
 33. The structure of claim 26 wherein the single lensencapsulates the LED and the one or more semiconductor dice.
 34. A lightemitting diode (LED) structure comprising: an LED mounted on asubstrate: a first lens molded over and encapsulating the LED, the lenshaving a substantially flat top; and a prefabricated second lens affixedto the substantially flat top of the first lens.
 35. The structure ofclaim 34 wherein the second lens is a collimating lens.
 36. Thestructure of claim 34 wherein the second lens is a Fresnel lens.
 37. Thestructure of claim 34 wherein the first lens has wall portionssurrounding the substantially flat top such that a top of the wallportions is substantially coplanar with a top of the second lens. 38.The structure of claim 37 wherein the wall portions are angled toreflect light from sides of the second lens away from the LED.
 39. Thestructure of claim 34 wherein a surface of the second lens isapproximately a same size as a surface of the LED.
 40. The structure ofclaim 34 wherein the first lens contains phosphor and light from the LEDenergizes the phosphor and mixes with light generated by the phosphor.41. The structure of claim 34 wherein the structure emits white light.42. The structure of claim 41 wherein the structure is a flash in acamera.
 43. The structure of claim 34 wherein the first lens comprisessilicone.
 44. A process for forming a light emitting diode (LED)structure comprising: mounting an LED on a submount, wherein at least afirst electrode on the LED is bonded to at least a second electrode on asurface of the submount, a void existing between the LED and the surfaceof the submount; filling the void with an underfill material; providinga mold having an indention corresponding to a lens; filling theindention with a liquid lens material; after the step of filling,immersing the LED and the underfill material into the liquid lensmaterial in the mold, the underfill preventing the liquid lens materialfrom entering the void; curing the liquid lens material to encapsulatethe LED and underfill material with a molded lens; and removing the LEDwith the molded lens from the mold.
 45. The method of claim 44 wherein atransparent substrate forms a top surface of the LED, wherein a portionof the underfill material is disposed on side surfaces of the LED,including the substrate. 46-49. (canceled)
 50. A light emitting diode(LED) structure comprising: an LED on a submount; a molded first lensover the LED, wherein the molded first lens has a plasma treated outersurface; a molded second lens formed directly over the first lens,wherein the plasma treated outer surface of the first lens increasesadherence of the first lens to the second lens.
 51. A process forforming a light emitting diode (LED) structure comprising: providing anarrangement of a plurality of LED dies mounted on a single submountsubstrate; providing a first mold having first indentions in anarrangement corresponding to the arrangement of the plurality of LEDdies, each first indentation corresponding to outer dimensions of afirst lens to be formed over each of the LED dies mounted on thesubmount substrate; aligning the submount substrate with respect to thefirst mold; molding first lenses, not containing a phosphor, directlyover each of the LED dies using the first mold; providing a second moldhaving second indentions in an arrangement corresponding to thearrangement of the plurality of LED dies, each second indentationcorresponding to outer dimensions of a second lens to be formed overeach of the LED dies mounted on the submount substrate, dimensions ofeach second indention being larger than dimensions of each firstindention; aligning the submount substrate with respect to the secondmold; and molding second lenses, containing a phosphor, over each of theLED dies and first lenses using the second mold; whereby innerdimensions of the second lenses over the LED dies are defined by outerdimensions of the first lenses over the LED dies, such that identicalmisalignments of the submount substrate with respect to the first moldand the second mold, within a range, do not affect a thickness of thesecond lenses.
 52. The process of claim 51 wherein molding clear firstlenses, not containing a phosphor, over each of the LED dies using thefirst mold comprises: filling the first indentions with a first liquidlens material not containing a phosphor, prior to aligning the submountsubstrate with respect to the first mold; immersing all the LED diessimultaneously into the first liquid lens material in the first mold;and curing the first liquid lens material to form the first lens overeach of the LED dies; and wherein molding second lenses, containing aphosphor, over each of the LED dies and first lenses using the secondmold comprises: filling the second indentions with a second liquid lensmaterial containing a phosphor, prior to aligning the submount substratewith respect to the second mold; immersing all the LED dies and firstlenses simultaneously into the second liquid lens material in the secondmold; and curing the second liquid lens material to form the second lensover each of the LED dies and over each of the first lenses.
 53. Theprocess of claim 51 further comprising dicing the substrate to formindividual LED structures.
 54. The process of claim 51 furthercomprising molding one or more additional lenses over the second lenses.55. The process of claim 51 wherein the phosphor in the second lenses,in conjunction with light emitted by the LED dies, generates whitelight.
 56. A light emitting diode (LED) structure comprising: an LED diemounted on a submount substrate: a first lens molded directly over theLED die using a first mold aligned to the substrate, the first lenscontaining no phosphor; and a second lens molded directly over the firstlens using a second mold aligned to the substrate, the second lenscontaining a phosphor, whereby inner dimensions of the second lens overthe LED die are defined by outer dimensions of the first lens over theLED die, such that identical misalignments of the substrate with respectto the first mold and the second mold, within a range, do not affect athickness of the second lens.